rac-1,2,3,4-Tetrahydro-1,4-methanoanthracene-6,7-dicarbonitrile

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rac-1,2,3,4-Tetra­hydro-1,4-methano­anthracene-6,7-dicarbonitrile

The title compound, C(17)H(12)N(2), comprises a norbornane unit having a dicyanona-phthalene ring fused on one side. Both cyano groups are twisted slightly out of the plane of the naphthalene ring system [C-C-C-C torsion angle = 1.9 (2)°]. In the crystal, inversion-related mol-ecules are linked by pairs of weak C-H⋯N hydrogen bonds, forming dimers.

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In the title compound, C16H15NO2S [alternative name: rac-2,3-diphenyl-1,3-thia-zinan-4-one 1-oxide], the thia-zine ring exhibits an envelope conformation, with the S atom forming the flap. The sulfoxide O atom is in a pseudo-axial position on the thia-zine ring and is trans to the phenyl group on C-2. The phenyl rings form a dihedral angle of 89.47 (19)°. In this racemate crystal, homochiral mo...

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2,5-Diamino­thio­phene-3,4-dicarbonitrile

In the title compound, C(6)H(4)N(4)S, the planar mol-ecule lies across a crystallographic mirror plane. In the crystal, the mol-ecules form centrosymmetric dimers through cyclic amino N-H⋯N hydrogen-bonding associations with cyano N-atom acceptors [graph set R(2) (2)(12)] and these dimers are extended through amine-cyano N-H⋯N associations into a three-dimensional network.

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4,5-Diamino­benzene-1,2-dicarbonitrile

The mol-ecular skeleton of the title mol-ecule, C(8)H(6)N(4), is essentially planar [maximum deviation from the mean plane of 0.037 (2) Å]. All N atoms are involved in the formation of inter-molecular N-H⋯N hydrogen bonds. The crystal packing exhibits also dipole-dipole inter-actions between the cyano groups of neighbouring mol-ecules [C⋯C 3.473 (2) Å].

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2011

ISSN: 1600-5368

DOI: 10.1107/s1600536811047611